Energy Applications /rasei/ en Thermally Stable Anthracene-Based 2D/3D Heterostructures for Perovskite Solar Cells /rasei/2024/12/27/thermally-stable-anthracene-based-2d3d-heterostructures-perovskite-solar-cells Thermally Stable Anthracene-Based 2D/3D Heterostructures for Perovskite Solar Cells Daniel Morton Fri, 12/27/2024 - 20:38 Categories: Publication Tags: Barlow Energy Applications Energy Generation Marder Nanoscience and Advanced Materials Perovskites Solar Power Toney ACS APPLIED MATERIALS & INTERFACES, 2024, ASAP window.location.href = `https://doi.org/10.1021/acsami.4c17382`;

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Sat, 28 Dec 2024 03:38:26 +0000 Daniel Morton 1222 at /rasei
2024 Nozik Lecture | Matt Beard /rasei/2024/12/20/2024-nozik-lecture-matt-beard 2024 Nozik Lecture | Matt Beard Daniel Morton Fri, 12/20/2024 - 19:09 Categories: Nozik Lecture Tags: Beard Energy Applications Nanoscience and Advanced Materials Nozik Find out more

The Arthur Nozik Lecture Series honors the research and career of Prof. Nozik, who has been a leader in the thriving ecosystem of renewable energy research that has developed along the front range over the last four decades. This lecture was recorded on December 9, 2024.

Biography:

Matthew C. Beard is a senior laboratory research fellow at the National Renewable Energy Laboratory (NREL) and Director of the Center for Hybrid Organic Inorganic Semiconductors for Energy (CHOISE) and Energy Frontier Research Center (EFRC) funded by the Office of Science within DOE.  Beard is also a Fellow of the Renewable and Sustainable Energy Institute a joint research institute between NREL and CU Boulder and an Adjoint professor within the Chemistry department of Colorado School of Mines.  Beard has been at NREL since 2003 (working for Arthur Nozik) and before that graduated from the Yale Chemistry Department where he received his Ph.D. degree developing non-contact ultrafast probes of carrier dynamics in semiconductors and semiconductor nanocrystals with Charlie Schmuttenmaer.  Beard also served as Associate director for the Center for Advanced Solar Photophysics.  Beard is a fellow of the AAAS, American Physical Society, and the Royal Society of Chemistry. Beard is listed a Clarivate highly cited researcher from 2023-2018 with over 200 publications.  Beard was awarded the 2020 H.M. Hubbard award, the 2022 E.O. Lawarence Award from DOE, the RSC Chemical Dynamics award, and NREL’s highest impact paper in 2024.  Beard serves on the editorial boards of Phyiscal Review Letters (divisional editor), ACS Energy Letters and Journal of Chemical Physics.  He has 10 patents and patent applications under review and given  > 150 invited presentations, including being named the 2024 Alexander Cruickshank Gordon research conference lecturer, the 2022 McElvain lecturer at U. of Wisconsin, and the 2024 William Chupka Lecturer at Yale University.

12/09/2024

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Sat, 21 Dec 2024 02:09:36 +0000 Daniel Morton 1214 at /rasei
Catalyzing the Sustainable Decomposition of PFAS Forever Chemicals /rasei/2024/12/20/catalyzing-sustainable-decomposition-pfas-forever-chemicals Catalyzing the Sustainable Decomposition of PFAS Forever Chemicals Daniel Morton Fri, 12/20/2024 - 17:30 Categories: News Publication Highlight Tags: Catalysis Damrauer Energy Applications Energy Impacts Polymers SUPRCAT Daniel Morton

RASEI Fellow Niels Damrauer is part of a collaborative team that have developed a new light-driven C-F activation reaction, one that has the potential to help dismantle PFAS ‘forever chemicals’

Find out more

 

Perfluoroalkyl and polyfluoroalkyl substances, or PFAS, are synthetic compounds that have found widespread use in consumer products and industrial applications. Their water and grease resistant properties have been part of their attraction in their applications, but these are also the reason that they are now found practically everywhere in the environment, they are very difficult to decompose.

While many chemicals will decompose relatively quickly, studies have shown that PFAS are expected to stick around for up to 1000 years. While this durability is great in something like firefighting foams or non-stick cookware, it is not great when these compounds get into the environment.

This new article, published in Nature in November of 2024, describes the work of a collaborative team of theoretical and experimental chemists, who have developed a new photochemical reaction that could hold promise of speeding up the decomposition of PFAS. A recent highlight of this work, written by the graduate student and postdoctoral fellows who did the research, appeared in The Conversation.

Using a photocatalyst, that absorbs light to speed up a reaction, the researchers were able to ‘activate’ one of the carbon-fluorine bonds, one of the strongest bonds in organic chemistry. The photocatalyst absorbs light, transfers electrons to the fluorine containing molecules, which then breaks down the sturdy carbon-fluorine bond.

While this doesn’t decompose the whole molecule, it is essentially like finding a chink in the armor, it opens the door to degradation of the PFAS to harmless smaller molecules.

This study demonstrated this process on a small scale, and the researchers are looking at how to optimize this reaction so it is more robust and can be done on larger scales. This work is part of a National Science Foundation funded Center for Chemical Innovation called SuPRCat, a research community that will be looking at this challenge, among others.

If it is possible to break down these forever chemicals, it will help prevent these environmental pollutants being in our soil, rivers, and drinking water. Excited to see the next steps from the team!

December 2024

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Sat, 21 Dec 2024 00:30:44 +0000 Daniel Morton 1213 at /rasei
Intrinsically Slow Cooling of Hot Electrons in CdSe Nanocrystals Compared to CdS /rasei/2024/12/18/intrinsically-slow-cooling-hot-electrons-cdse-nanocrystals-compared-cds Intrinsically Slow Cooling of Hot Electrons in CdSe Nanocrystals Compared to CdS Daniel Morton Wed, 12/18/2024 - 20:43 Categories: Publication Tags: Dukovic Energy Applications Nanoscience and Advanced Materials NANO LETTERS, 2024, ASAP window.location.href = `https://doi.org/10.1021/acs.nanolett.4c04912`;

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Thu, 19 Dec 2024 03:43:53 +0000 Daniel Morton 1224 at /rasei
Tutorial on In Situ and Operando (Scanning) Transmission Electron Microscopy for Analysis of Nanoscale Structure–Property Relationships /rasei/2024/12/17/tutorial-situ-and-operando-scanning-transmission-electron-microscopy-analysis-nanoscale Tutorial on In Situ and Operando (Scanning) Transmission Electron Microscopy for Analysis of Nanoscale Structure–Property Relationships Daniel Morton Tue, 12/17/2024 - 20:41 Categories: Publication Tags: Energy Applications Nanoscience and Advanced Materials Spurgeon ACS NANO, 2024, 18, 52, 35091-35103 window.location.href = `https://doi.org/10.1021/acsnano.4c09256`;

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Wed, 18 Dec 2024 03:41:20 +0000 Daniel Morton 1223 at /rasei
In Situ Characterization of the Oxidation Behavior of Carbonate-Based Electrolytes for Lithium-Ion Batteries by Scanning Electrochemical Microscopy /rasei/2024/12/04/situ-characterization-oxidation-behavior-carbonate-based-electrolytes-lithium-ion In Situ Characterization of the Oxidation Behavior of Carbonate-Based Electrolytes for Lithium-Ion Batteries by Scanning Electrochemical Microscopy Daniel Morton Wed, 12/04/2024 - 20:34 Categories: Publication Tags: Batteries Energy Applications Energy Storage Nanoscience and Advanced Materials Tenent Toney ACS ELECTROCHEMISTRY, 2024 window.location.href = `https://doi.org/10.1021/acselectrochem.4c00106`;

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Thu, 05 Dec 2024 03:34:55 +0000 Daniel Morton 1221 at /rasei
Manipulating Backbone Planarity of Ester Functionalized Conjugated Polymer Constitutional Isomer Derivatives Blended with Molecular Acceptors for Controlling Photovoltaic Properties /rasei/2024/11/26/manipulating-backbone-planarity-ester-functionalized-conjugated-polymer-constitutional Manipulating Backbone Planarity of Ester Functionalized Conjugated Polymer Constitutional Isomer Derivatives Blended with Molecular Acceptors for Controlling Photovoltaic Properties Daniel Morton Tue, 11/26/2024 - 20:47 Categories: Publication Tags: Energy Applications Marder Nanoscience and Advanced Materials Semiconductors Toney CHEMISTRY OF MATERIALS, 2024, 36, 23, 11656-11668 window.location.href = `https://doi.org/10.1021/acs.chemmater.4c02751`;

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Wed, 27 Nov 2024 03:47:24 +0000 Daniel Morton 1225 at /rasei
Bulk Layering Effects of Ag and Cu for Tandem CO2 Electrolysis /rasei/2024/11/25/bulk-layering-effects-ag-and-cu-tandem-co2-electrolysis Bulk Layering Effects of Ag and Cu for Tandem CO2 Electrolysis Daniel Morton Mon, 11/25/2024 - 20:31 Categories: Publication Tags: Carbon Capture Catalysis Energy Applications Smith CHEMSUSCHEM, 2024, e202401769 window.location.href = `https://doi.org/10.1002/cssc.202401769`;

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Tue, 26 Nov 2024 03:31:02 +0000 Daniel Morton 1220 at /rasei
Photocatalytic C–F bond activation in small molecules and polyfluoroalkyl substances /rasei/2024/11/20/photocatalytic-c-f-bond-activation-small-molecules-and-polyfluoroalkyl-substances Photocatalytic C–F bond activation in small molecules and polyfluoroalkyl substances Daniel Morton Wed, 11/20/2024 - 11:50 Categories: Publication Tags: Catalysis Computational Modeling Damrauer Energy Applications Energy Impacts Polymers SUPRCAT NATURE, 2024
window.location.href = `https://doi.org/10.1038/s41586-024-08327-7`;

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Wed, 20 Nov 2024 18:50:57 +0000 Daniel Morton 1205 at /rasei
2024 Clarivate Highly Cited Researcher Awards /rasei/2024/11/19/2024-clarivate-highly-cited-researcher-awards 2024 Clarivate Highly Cited Researcher Awards Daniel Morton Tue, 11/19/2024 - 13:12 Categories: News Recognition Tags: Beard Berry Energy Applications Energy Generation Luther McGehee Toney Find out more:

Five RASEI Fellows awarded the Highly Cited Researcher designation by Clarivate.

Each year Clarivate analyzes the citations of articles from researchers from across the sciences. From this analysis Clarivate highlights the researchers who have authored multiple highly cited papers which rank in the top 1% by citations for their field(s) and publication year in the Web of Science over the past decade.

This year five RASEI Fellows featured in the 2024 Highly Cited Researcher list, which includes 6,886 researchers. This year Matt Beard, Joe Berry, Joey Luther, Mike McGehee and Mike Toney were selected. For Matt, Mike and Joey, this is the fifth year in the row, the fourth year in a row for Joe Berry and the third year in a row for Mike Toney.

Congratulation to everyone for the recognition of the impact of their research. 

11/19/2024

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Tue, 19 Nov 2024 20:12:12 +0000 Daniel Morton 1190 at /rasei